Tetrahedral bond length and angle variations in germanates
- 1 January 1977
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 30 (8) , 1673-1684
- https://doi.org/10.1071/ch9771673
Abstract
Individual Ge-O bond lengths of 24 germanate tetrahedra in solid materials are observed to increase with decreasing 3, the average of the three O-Ge-O angles common to each bond, and with 1/cos(Ge-O-Ge). These correlations are examined in terms of valence electron population analyses obtained from extended Huckel molecular orbital theory.Keywords
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