Synthesis, X-ray structure, and chemical properties of [Cu8(dmpz)8(OH)8](Hdmpz = 3,5-dimethylpyrazole). First example of a copper complex containing a planar ring of eight metal atoms
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1021-1023
- https://doi.org/10.1039/c39900001021
Abstract
Reaction of the polymeric copper(I)-3,5-dimethylpyrazolate, [Cu(dmpz)]n, with molecular dioxygen gives the octameric copper(II) complex, [Cu8(dmpz)8(OH)8], whose spectroscopic and chemical properties, and X-ray structure analysis are reported.Keywords
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