THE MOLECULAR STRUCTURE OF THE ALKOXO-OXYGEN BRIDGED BINUCLEAR COPPER (II) COMPLEX, [Cu2{(CH3)2N(CH2)3NH(CH2)2O}2(CH3OH)2](ClO4)2
- 1 April 1979
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 9 (2) , 133-137
- https://doi.org/10.1080/00958977908076517
Abstract
The molecular structure of the title compound has been determined from single-crystal X-ray diffraction methods. The molecule consists of an alkoxo-oxygen bridged dimeric unit, [Cu2{(CH3)2 N(CH2)3 NH(CH2)2O}2 (CH3OH)2]2+, and two perchlorate anions as counter ions. The coordination geometry of each copper ion is a five coordinated tetragonal pyramid, of which the apical site is occupied by the oxygen atom of methanol. The magnetic moment of the compound is remarkably higher than that expected from Cu[sbnd]O[sbnd]Cu angle. This is explained in terms of the effect of axial coordination.Keywords
This publication has 17 references indexed in Scilit:
- Thiocyanato(2-dipropylaminoethanolato)copper(II)Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1977
- The Crystal Structure and Magnetic Property of the Alkoxo-Oxygen Bridged Tetranuclear Copper(II) Complex, Cu4{(n-C3H7)2N(CH2)2O}4Cl4Bulletin of the Chemical Society of Japan, 1976
- Alkoxo-bridged copper(II) complexesJournal of Inorganic and Nuclear Chemistry, 1976
- Kristallstrukturen von Chloro- und γ-Bromo-(2-dibutylaminoäthanolato)-kupfer(II)Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1975
- Copper(II) complexes of amino alcohols. Molecular structures of chloro(2-diethylaminoethanolato)copper(II) and bromo(2-dibutylaminoethanolato)copper(II)Inorganic Chemistry, 1975
- Correlation between magnetic and spectral properties of alkoxo-bridged copper(II) complexes with N,N-dialkyldiaminealcohols and N,N-dialkylaminoalcoholsInorganica Chimica Acta, 1974
- Copper(II) Complexes with Some Aliphatic DiaminealcoholsBulletin of the Chemical Society of Japan, 1973
- Kristall‐ und Molekülstrukturen von Halogeno(2‐diäthylamino‐äthanolato)kupfer(II)‐Komplexen (Halogen: Chlor und Brom)European Journal of Inorganic Chemistry, 1973
- Absorption Band in the Near-Ultraviolet Region Observed for Binuclear Copper(II) ComplexesBulletin of the Chemical Society of Japan, 1973
- Copper(II) Complexes with Subnormal Magnetic MomentsChemical Reviews, 1964