Solvothermal synthesis of [Cr10(μ-O2CMe)10(μ-OR)20] ‘chromic wheels’ with antiferromagnetic (R = Et) and ferromagnetic (R = Me) Cr(iii)···Cr(iii) interactions

Abstract
Two decanuclear cyclic Cr(III) complexes have been synthesised in high yield by solvothermal techniques: magnetic susceptibility studies reveal ferromagnetic Cr⋯Cr exchange in one, and antiferromagnetic Cr⋯Cr exchange in the other.

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