Electrochemically Promoted C−N Bond Formation from Acetylenic Amines and CO2. Synthesis of 5-Methylene-1,3-oxazolidin-2-ones
- 12 August 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 70 (19) , 7795-7798
- https://doi.org/10.1021/jo0511804
Abstract
An efficient electrochemical synthesis of 5-methylene-1,3-oxazolidin-2-ones (2a−h) from acetylenic amines (1a−h) and carbon dioxide has been achieved by direct electrolysis of solution of MeCN and Et4NPF6 containing the amine, with subsequent CO2 bubbling and heating. The yields vary from good to excellent, the conditions are mild, and the use of toxic and harmful chemicals and catalysts is avoided.Keywords
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