The first hexacarboxylato diruthenium(III) complex. Synthesis, X-ray crystal structure, and properties of tetra-µ-acetato-diacetatodiruthenium(III) monohydrate
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1385-1387
- https://doi.org/10.1039/c39870001385
Abstract
The reaction of [Ru2(µ-OAc)4Cl] with AgOAc in AcOH/MeOH gives the red oxidation product [Ru2(µ-OAc)4(OAc)2]·H2O (1), the structure of which has been determined by X-ray crystallography; this is the first example of a paramagnetic Ru2 6+ complex.Keywords
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