Cobalt(II), rhodium(III), and iridium(III) complexes of 1,2-dithiocyanatoethane

1 January 1967

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 203-204
https://doi.org/10.1039/j19670000203

Abstract

1,2-Dithiocyanatoethane forms polynuclear complexes with cobalt(II) halides, of general formula [CoX₂·L](X = Cl, Br, or I), which are decomposed completely by unidentate ligands. Rhodium(III) and iridium(III) form binuclear halogen-bridged complexes of general formula [MX₃·L](M = Rh or Ir; X = Cl, Br, or I). The halogen-bridges are split by unidentate ligands. Infrared spectra are recorded, and structures of the complexes discussed.

Keywords

RHODIUM
DITHIOCYANATOETHANE
IRIDIUM
III
COBALT
STRUCTURES
COX2
HALIDES
SPLIT

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