Investigation on the enantiomeric impurity of epinephrine hydrochloride injections

Abstract
Epinephrine enantiomers were derived into diastereoisomers with the chiral reagent 2,3,4,6‐tetra‐O‐acetyl‐β‐D‐glucopyranosylisothiocyanate. The resolutions was carried out on a C18 column. The RS between (−)‐R‐ and (+)‐S‐isomers was 2.3. The retention time could be changed by adding a proper amount of acetonirile into the mobile phase. The results showed that (+)‐S‐isomer in the epinephrine hydrochloride injections increased during the period of storage.

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