Polarographic and voltammetric determination of 1-(2’-carbamoylphenyl)-3,3-dimethyltriazene

1 January 1991

journal article
Published by Institute of Organic Chemistry & Biochemistry in Collection of Czechoslovak Chemical Communications

Vol. 56 (10) , 2073-2081
https://doi.org/10.1135/cccc19912073

Abstract

A study was carried out of the polarographic behaviour of the genotoxic substance 1-(2’-carbamoylphenyl)-3,3-dimethyltriazene and optimum conditions were found for its determination by tast polarography or differential pulse polarography at a static mercury drop electrode and by fast scan differential pulse voltammetry at a hanging mercury drop electrode in the concentration range 1 . 10^-4 -2 . 10^-7 mol 1^-1. The sensivity of the determination can be further improved through adsorptive accumulation of the test substance on the surface of the hanging mercury drop electrode; five-minute accumulation in unstirred solution permits determination in the concentration range (2-10 . 10^-8 mol 1^-1 and two-minute accumulation in stirred solution allows determination in the range (2-10) . 10^-9 mol 1^-1.

Keywords

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