Spin Trapping of Benzoyloxycyclohexadienyl Radicals by 2,3,5,6-Tetramethylnitrosobenzene (Nitrosodurene) in the Decomposition of Dibenzoyl Peroxide in Benzene
- 1 September 1976
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 49 (9) , 2594-2595
- https://doi.org/10.1246/bcsj.49.2594
Abstract
The aroyloxycyclohexadienyl radicals (VIII), the key intermediates iates in the homolytic aromatic aroyloxylation, were detected and identified in the decomposition of dibenzoyl peroxide, bis(4-methylbenzoyl) peroxide, and bis(4-methoxybenzoyl) peroxide in benzene-d6 as spin adducts of nitrosodurene.Keywords
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