Controlled trans‐stereospecific polymerization of isoprene with lanthanide(III) borohydride/dialkylmagnesium systems: The improvement of the activity and selectivity, kinetic studies, and mechanistic aspects
- 14 May 2007
- journal article
- Published by Wiley in Journal of Polymer Science Part A: Polymer Chemistry
- Vol. 45 (12) , 2400-2409
- https://doi.org/10.1002/pola.22002
Abstract
No abstract availableKeywords
This publication has 32 references indexed in Scilit:
- Borohydrido Rare Earth Complexes as Precatalysts for the Polymerisation of StyreneZeitschrift für anorganische und allgemeine Chemie, 2006
- Mixed Aluminum‐Magnesium‐Rare Earth Allyl Catalysts for Controlled Isoprene Polymerization: Modulation of StereocontrolMacromolecular Rapid Communications, 2006
- Lanthanide borohydrido complexes for MMA polymerization: syndio‐ vs iso‐ stereocontrolApplied Organometallic Chemistry, 2005
- Activity and Microstructure Variations with Temperature in Conjugated Diene Polymerizations Catalyzed by CpTiCl3−MAOMacromolecules, 2005
- Highly trans-Stereospecific Isoprene Polymerization by Neodymium Borohydrido CatalystsMacromolecules, 2005
- Living and non-living Ziegler–Natta catalysts: electronic properties of active sitePolymer, 2003
- Lanthanidocene Catalysts for the Homo‐ and Copolymerization of Ethylene with ButadieneMacromolecular Chemistry and Physics, 2003
- Structure of active centers, their stereospecificity distribution, and multiplicity in diene polymerization initiated by NdCl3‐based catalytic systemsJournal of Applied Polymer Science, 2003
- Highly Active Single-Site Catalysts for the 1,4-cis Polymerization of Butadiene from Allylneodymium(III) Chlorides and Trialkylaluminiums – A Contribution to the Activation of Tris(allyl)neodymium(III) and the Further Elucidation of the Structure-Activity RelationshipMacromolecular Chemistry and Physics, 2002
- Synthesis and X-ray Crystal Structures of (C5HiPr4)Ln(BH4)2(THF)(Ln = Nd and Sm), Versatile Precursors for Polymerization CatalystsEuropean Journal of Inorganic Chemistry, 2000