Reactions of hexafluoroacetone, hexafluoropropene, and tetrafluoroethylene with bis(cyclo-octa-1,5-diene)platinum; molecular structure of [Pt2{(CF3)2CO}(1,5-C8H12)2]
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 451-452
- https://doi.org/10.1039/c39750000451
Abstract
Treatment of [Pt(COD)2](COD = cyclo-octa-1,5-diene) with hexafluoroacetone affords dinuclear or mononuclear platinum complexes, whereas tetrafluoro-ethylene gives a stereochemically non-rigid octafluoro-1,4-diplatinacyclohexane, and hexafluoropropene yields a dinuclear carbene-bridged complex.Keywords
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