Towards synthetic enzymes based on porphyrins and steroids
Open Access
- 1 January 1994
- journal article
- Published by Walter de Gruyter GmbH in Pure and Applied Chemistry
- Vol. 66 (4) , 803-810
- https://doi.org/10.1351/pac199466040803
Abstract
The molecular recognition properties of three systems are discussed: a self-associating cyclocholate; a porphyrin-cyclocholate molecular bowl which recognises morphine enantioselectively; and a cyclic porphyrin trimer which efficiently and stereoselectively accelerates a Diels-Alder reaction.Keywords
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