C–H allylic bond cleavage to generate an active hydridopalladium species for the alkoxycarbonylation of alkenes. X-Ray crystal structure of [(Ph3PCH2CHCHPh)4(PdCl6)(SnCl6)]
- 1 January 1993
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 747-750
- https://doi.org/10.1039/c39930000747
Abstract
On the basis of a reactivity study using various alkenes and of the X-ray crystal structure analysis of the title compound isolated from the alkoxycarbonylation reaction, the formation of an active Pd(H)(SnCl3) species, generated from the [PdCl2(PPh3)2]SnCl2–PPh3 system, is proposed.Keywords
This publication has 6 references indexed in Scilit:
- Carbon monoxide as a building block in organic synthesisJournal of Molecular Catalysis, 1993
- Lactonization of unsaturated alcohols catalyzed by palladium complexes under neutral conditionsThe Journal of Organic Chemistry, 1991
- On the mechanism of the hydrocarbalkoxylation of olefins catalyzed by palladium complexesJournal of Organometallic Chemistry, 1990
- Carbon monoxide as a building block for organic synthesisJournal of Molecular Catalysis, 1990
- Allylic Complexes of Palladium(II)Published by Elsevier ,1982
- Reactions of palldium(II) compounds with carbon monoxide in alcohol/amine systems : a new route to palladium(O) carbonyl and carboalkoxy-palladium(II) complexesJournal of Organometallic Chemistry, 1973