Synthesis of [3.3.3]propellanes by ‘exocyclic’ transannular cycloaddition of olefinic methylenecyclopropanes
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1112-1113
- https://doi.org/10.1039/c39880001112
Abstract
Olefinic methylenecyclopropanes undergo quantitative transannular ring closure under catalysis by Group 10 metals to give [3.3.3]propellanes, through cycloaddition of a trimethylenemethane-like intermediate.Keywords
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