MECHANISM FOR THE HYDROPEROXIDE-MEDIATED INACTIVATION OF PROSTACYCLIN SYNTHETASE

  • 1 January 1979
    • journal article
    • research article
    • Vol. 53  (6) , 1191-1196
Abstract
Hydroxyl radical generation was demonstrated during heme-catalyzed decomposition of 15-hydroperoxy arachidonic acid. The hydroperoxide-mediated inactivation of prostacyclin synthetase in bovine aorta microsome preparations seems to be related to the generation of this highly reactive species. A relationship between hydroperoxides and the hydroxyl radical may be important in the modulation of prostacyclin synthesis in diseased states [e.g., platelet-mediated endothelial cell injury].