The Spontaneous Resolution of Oxalatobis(ethylenediamine)cobalt(III) Chloride
- 15 March 1971
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 49 (6) , 965-967
- https://doi.org/10.1139/v71-156
Abstract
The spontaneous partial resolution of oxalatobis(ethylenediamine)cobalt(III) chloride was affected by the crystallization of the complex compound from a supersaturated aqueous solution (1 g/25 ml) at 20 °C without the influence of any dissymmetric agent. Crystals exhibiting in some cases dextro-rotatory properties, and in the others levo-rotatory were obtained with up to 25% optical purity.Keywords
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