Non-Sequential Processes for the Transformation of a Racemate into a Single Stereoisomeric Product: Proposal for Stereochemical Classification
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- 16 November 2001
- journal article
- concept
- Published by Wiley in Chemistry – A European Journal
- Vol. 7 (23) , 5004-5010
- https://doi.org/10.1002/1521-3765(20011203)7:23<5004::aid-chem5004>3.0.co;2-x
Abstract
Non‐sequential processes which allow the transformation of a racemate into a single stereoisomeric product without the occurrence of an “undesired” isomer are classified according to their underlying stereochemistry. A re‐definition of the term “de‐racemization” is proposed.Keywords
This publication has 65 references indexed in Scilit:
- Dynamic Kinetic Resolution of Secondary Diols via Coupled Ruthenium and Enzyme CatalysisThe Journal of Organic Chemistry, 1999
- NAD+-Dependent (S)-Specific Secondary Alcohol Dehydrogenase Involved in Stereoinversion of 3-Pentyn-2-ol Catalyzed byNocardia fuscaAKU 2123Bioscience, Biotechnology, and Biochemistry, 1999
- Dynamic kinetic resolution in the hydrolysis of an α-bromo esterChemical Communications, 1998
- Enzymatische Racematspaltung von Alkoholen gekoppelt mit Ruthenium‐katalysierter Racemisierung des Substrat‐AlkoholsAngewandte Chemie, 1997
- Lipase–triethylamine-mediated dynamic transesterification of a tricyclic acyloin having a latent meso-structure: a new route to optically pure oxodicyclopentadieneChemical Communications, 1997
- Dynamic resolutions in asymmetric synthesisChemical Society Reviews, 1996
- Conversion of a Cyanhydrin Compound intoS-(−)-3-Phenyllactic Acid by Enantioselective Hydrolytic Activity ofPseudomonassp. BC-18Bioscience, Biotechnology, and Biochemistry, 1996
- Extension of chromatographically-derived molecular recognition concepts to first order asymmetric transformationsJournal of the American Chemical Society, 1987
- Kinetic resolution of racemic allylic alcohols by enantioselective epoxidation. A route to substances of absolute enantiomeric purity?Journal of the American Chemical Society, 1981
- Über einen neuen Effekt in Lösungen optisch‐aktiver SubstanzenBerichte der deutschen chemischen Gesellschaft (A and B Series), 1932