Oxidation of enamines derived from sugars
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 11,p. 1923-1926
- https://doi.org/10.1039/p19890001923
Abstract
The oxidation of sugar enamines with KMnO4–NaIO4 has been studied. The products depend on the extent of substitution of the enaminic double bond. For 2′-monosubstituted enamines, N-formyl or N-acyl amino sugars are obtained, whereas the 2,2′-disubstituted substrates afforded α-hydroxy amides, together with those products of double-bond cleavage. Z–E Isomerism in the N-formyl amino sugars has been observed.This publication has 2 references indexed in Scilit:
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- Antigenic S-type lipopolysaccharide of Brucella abortus 1119-3Infection and Immunity, 1984