A new synthetic method for .BETA.,.GAMMA.-unsaturated ketones and a total synthesis of egomaketone.

1 January 1982

journal article
Published by Pharmaceutical Society of Japan in CHEMICAL & PHARMACEUTICAL BULLETIN

Vol. 30 (3) , 1106-1109
https://doi.org/10.1248/cpb.30.1106

Abstract

A new method for preparing β, γ-unsaturated ketones based on the intramolecular acyl N to C transfer of 2-carboxamidephenylsulfides is described including a total synthesis of egomaketone using this method.

Keywords

ACYL
INTRAMOLECULAR
BETA
GAMMA
CARBOXAMIDEPHENYLSULFIDES
NEW SYNTHETIC METHOD

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