Alkylation of active methylene compounds by allylic alcohols using tetrakis(triphenylphosphine)palladium(0) catalysts

1 January 1989

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 13,p. 883-884
https://doi.org/10.1039/c39890000883

Abstract

We have found that active methylene compounds can be alkylated by allylic alcohols using (PPh₃)₄Pd as a catalyst at 100 °C without prior activation of the allylic hydroxy group.

Keywords

ACTIVE METHYLENE
COMPOUNDS
PRIOR
PALLADIUM
4PD
TETRAKIS
TRIPHENYLPHOSPHINE
HYDROXY
PPH3

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