Solvothermal synthesis and structural characterisation of the first ammonium cobalt gallium phosphate hydrate, NH4[CoGa2P3O12(H2O)2]
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 6 (4) , 611-614
- https://doi.org/10.1039/jm9960600611
Abstract
The first ammonium cobalt gallium phosphate hydrate, NH4[CoGa2P3O12(H2O)2] has been prepared under solvothermal conditions and the structure determined using single-crystal X-ray diffraction [space group C2/c, a= 13.323(3), b= 10.245(1), c= 8.886(2)Å, β= 108.43(2)°, V= 1150.68 Å3, Z= 4]. The structure consists of GaO5, CoO6 and PO4 polyhedra linked to form a microporous three-dimensional framework containing channels in which the NH4 + cations reside.Keywords
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