Nucleophilic Displacement of Bis(perfluoroalkanoyl) Peroxides with Perfluoroalkanoate
- 1 July 1989
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 62 (7) , 2416-2418
- https://doi.org/10.1246/bcsj.62.2416
Abstract
Bis(perfluoroalkanoyl) peroxide ((RFCO2)2) suffered a nucleophilic displacement with perfluoroalkanoate (RF′CO2−) to give new mixed peroxide (RF(CO)OO(CO)RF′). When thiophene was reacted with bis(perfluoroalkanoyl) peroxide in the presence of pyridinium perfluoroalkanoate, not only the perfluoroalkyl group (RF) of the peroxide, but also perfluoroalkyl group (RF′) of perfluoroalkanoate, was introduced into thiophene.Keywords
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