Asymptotic behavior of atomic bound state wave functions
- 1 December 1973
- journal article
- research article
- Published by AIP Publishing in Journal of Mathematical Physics
- Vol. 14 (12) , 1860-1863
- https://doi.org/10.1063/1.1666258
Abstract
In the present paper we investigate the asymptotic properties of an exact bound state wave function φ of an n‐electron atomic system within the infinite nuclear mass approximation and neglecting relativistic effects. An explicit upper bound is derived for , where ri denotes the distance of the ith electron from the nucleus and μ = 1,2,3,⋯. We are then able to derive upper bounds for expressions like ‖h(ri)φ‖, where h (x) is an exponentially increasing function. We finally indicate an exponentially decreasing pointwise bound for φ.
Keywords
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