Geochemical stratigraphy of lava flows sampled by the Hawaii Scientific Drilling Project

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Abstract
Geochemical discriminants are used to place the boundary between Mauna Loa flows and underlying Mauna Kea flows at a depth of about 280 m. At a given MgO content the Mauna Kea flows are lower in SiO2 and total iron and higher in total alkali, TiO2, and incompatible elements than the Mauna Loa lavas. The uppermost Mauna Kea lavas (280 to 340 m) contain alkali basalts interlayered with tholeiites and correlate with the postshield Hamakua Volcanics. In addition to total alkalis, the alkali basalts have higher TiO2, P2O5, Sr, Ba, Ce, La, Zr, Nb, Y, and V relative to the tholeiites and lower Zr/Nb and Sr/Nb ratios. Some of the alkali basalts are extensively differentiated. Below 340 m all the flows are tholeiitic, with compositions broadly similar to the few “fresh” subaerial shield‐building Mauna Kea tholeiites studied to date. High‐MgO lavas are unusually abundant, although there is a wide range (7–28%) in MgO content reflecting olivine control. FeO/MgO relationships are used to infer parental picritic magmas with about 15 wt % MgO. Lavas with more MgO than this have accumulated olivine. The Mauna Loa lavas have compositional trends that are controlled by olivine crystallization and accumulation. They compare closely with trends for historical (1843–1984) flows, tending toward the depleted end of the spectrum. They are, though, much more MgO‐rich (9–30%) than is typical for most historical and young (<30 ka) prehistoric lavas. The unusual abundance of high‐MgO and picritic lavas is attributed to the likelihood that only large‐volume, hot, mobile flows will reach Hilo Bay from the northeast rift zone. FeO/MgO relationships are used to infer parental picritic magmas with about 17 wt % MgO. Again, lavas with more MgO than this have accumulated olivine. Systematic changes in incompatible element ratios are used to argue that the magma supply rate has diminished over time. On the other hand, the relatively constant Zr/Nb and Sr/Nb ratios that compare closely with historical and young (<30 kyr) prehistoric flows are used to argue that the source components for these lavas in the Hawaiian plume have remained relatively uniform over the last 100 kyr.