Time-dependent wave-packet forms of Schrödinger and Lippmann-Schwinger equations
- 28 February 1994
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 72 (9) , 1310-1313
- https://doi.org/10.1103/physrevlett.72.1310
Abstract
Time-independent wave-packet forms of the Schrödinger equation (TIWSE) and Lippmann-Schwinger equation (TIWLSB) have been derived by a partial time-to-energy Fourier transform of wave-packet solutions to the time-dependent Schrödinger equation. The new equations retain the initial wave packet χ() as a ‘‘universal source’’ of scattered waves, which applies for all collision energies E contained in the initial wave packet. The relationship between the solution (E) of the TIWSE or TIWLSE and the scattering solution (E) of the standard time-independent Lippmann-Schwinger or Schrödinger equation is given and the method illustrated by a computational application.
Keywords
This publication has 20 references indexed in Scilit:
- Dynamical basis sets for algebraic variational calculations in quantum-mechanical scattering theoryPhysical Review A, 1990
- The time-dependent Schrödinger equation: Application of absorbing boundary conditionsThe Journal of Chemical Physics, 1989
- Wave-packet approach to treat low energy reactive systems: accurate probabilities for hydrogen atom + hydrogenThe Journal of Physical Chemistry, 1989
- Quantum scattering via the log derivative version of the Kohn variational principleChemical Physics Letters, 1988
- Quantum mechanical algebraic variational methods for inelastic and reactive molecular collisionsThe Journal of Physical Chemistry, 1988
- ℒ2 amplitude density method for multichannel inelastic and rearrangement collisionsThe Journal of Chemical Physics, 1988
- New method for quantum reactive scattering, with applications to the 3-D H+H2 reactionChemical Physics Letters, 1987
- Bimolecular Reactive CollisionsPublished by American Chemical Society (ACS) ,1984
- Resonances in reactive collisions: Computational study of the H + H2 collisionChemical Physics Letters, 1971
- Quantum Mechanics of the H+H2 Reaction: Exact Scattering Probabilities for Collinear CollisionsThe Journal of Chemical Physics, 1970