Preparation and rearrangement of β-chloroalkyl aziridinylformates

Abstract
Several β-chloroalkyl chloroformates have been treated with aziridines (ethylenimine or propylenimine) to obtain excellent yields of β-chloroalkyl aziridinylformates. In each case, it was found that the aziridinylformates rearranged upon thermloysis to give good yields of N-(β-chloroalkyl)-2-oxazolidones.

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