Temperature-dependent hyperfine coupling constants in electron spin resonance. Part 4.—Out-of-plane vibrations of the ring protons in the cation of p-phenylenediamine

Abstract
The effect of out-of-plane vibrations on the temperature coefficient of the coupling constant of the ring protons in the radical cation of p-phenylenediamine is considered. In accordance with an earlier suggestion by the authors it is found that this mechanism adequately accounts for the experimental values of daH CH/dT in four different solvents.

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