Reactions of azobenzene and related compounds with rhodium complexes: cleavage of N:N and C:N bonds

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Abstract
The reactions of azobenzene and related compounds with rhodium complexes involve complexes containing chelated phenylazophenyl-2C,N′ ligands; complexes containing both RhI and RhIII; transition-metal promoted hydrogen-transfer reactions; and rhodium-assisted hydration of CHN bonds; a new catalytic reducing system is described.