Cobalt catalysed ring-opening carbonylation of cyclic ethers using N-(trimethylsilyl)amines
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1253-1254
- https://doi.org/10.1039/c39890001253
Abstract
N-(Trimethylsilyl)amines direct ring-opening carbonylation of a variety of cyclic ethers such as oxiranes (1–3), oxetane (4), tetrahydrofuran (5), and 1,3-dioxolane (6) in the presence of a catalytic amount of Co2(CO)8 under carbon monoxide pressure to give siloxy amides.Keywords
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