Fluxional behaviour of Rh4(CO)8{P(OPh)3}4: A 13C-{31P, 1H} NMR study
- 24 June 1980
- journal article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 192 (3) , 431-435
- https://doi.org/10.1016/s0022-328x(00)81235-8
Abstract
No abstract availableKeywords
This publication has 10 references indexed in Scilit:
- Stereochemical non-rigidity of a metal polyhedron; carbon-13 and platinum-195 fourier transform nuclear magnetic resonance spectra of [Ptn(CO)2n]2- (n = 3, 6, 9, 12 or 15)Journal of Organometallic Chemistry, 1979
- X-Ray crystal structure and dynamic behaviour of [Ir4(CO)11(CNBut)]Journal of the Chemical Society, Chemical Communications, 1979
- Mechanistic features of metal cluster rearrangementsChemical Reviews, 1978
- Electronic structure of M4(CO)12Hn and M4Cp4Hn complexesJournal of the American Chemical Society, 1978
- Structures of binary carbonyls and related compounds. Part 1. A new approach to fluxional behaviourJ. Chem. Soc., Dalton Trans., 1978
- Carbon-13 nuclear magnetic resonance spectra of polynuclear carbonyls of cobalt and rhodiumJ. Chem. Soc., Dalton Trans., 1978
- Synthesis and x-ray characterization of Rh4(CO)8 [P(OPh)3]4 and Rh6(CO)12[P(OPh)3]4Journal of Organometallic Chemistry, 1977
- Intracluster ligand mobility. 4. Solution structures and dynamics of Ir4(CO)12-x(PPh2Me)x (x = 1-4)Journal of the American Chemical Society, 1977
- Direct evidence from carbon-13 nuclear magnetic resonance for intramolecular scrambling of carbonyl groups in a metal atom cluster carbonyl, tetrarhodium dodecacarbonylJournal of the American Chemical Society, 1972
- A Solution to the Structural Dilemma of Co4(CO)12Based on Valence Tautomerism and Steric NonrigidityInorganic Chemistry, 1966