Shear-rate dependence of the viscosity of the Lennard-Jones liquid at the triple point
- 1 November 1991
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 44 (10) , 6936-6939
- https://doi.org/10.1103/physreva.44.6936
Abstract
High-precision molecular-dynamics (MD) data are reported for the shear viscosity η of the Lennard-Jones liquid at its triple point, as a function of the shear rate ε̇ for a large system (N=2048). The Green-Kubo (GK) value η(ε̇=0)=3.24±0.04 is estimated from a run of 3.6× steps (40 nsec). We find no numerical evidence of a long-time tail for the GK integrand (stress-stress time-correlation function). From our nonequilibrium MD results, obtained both at small and large values of ε̇, a consistent picture emerges that supports an analytical (quadratic at low shear rate) dependence of the viscosity on ε̇.
Keywords
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