Hard-sphere Yukawa fluid near a planar slit
- 15 November 1997
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 107 (19) , 8147-8151
- https://doi.org/10.1063/1.475078
Abstract
A density functional perturbative approximation, which is based on both the weighted-density approximation (WDA) of Tarazona and the density functional approximation of Rickayzen et al., has been employed to predict the density profiles of the hard-sphere attractive Yukawa fluid near a planar slit. The calculated density profiles show that the density functional perturbative approximation is a significant improvement upon those of the modified version of the Lovett–Mou–Buff–Wertheim (LMBW-1), which uses the exact contact value theorem, and compares very well with the computer simulation even for the low temperatures in the vicinity of the liquid–vapor fluid bulk transition.Keywords
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