Synthesis of the first example of a metal complex containing a co-ordinated µ₃-(η²-⊥) phospha-alkyne ligand. Addition of an Fe₂(CO)₆unit to the η²-phospha-alkyne complex [Pt(dppe)(Bu^tCP)]: crystal and molecular structure of [Fe₂Pt(dppe)(CO)₆(Bu_tCP)](dppe = Ph₂PCH₂CH₂PPh₂)

A new mode of co-ordination for a phospha-alkyne ligand has been established in the complex [Fe₂Pt(dppe)(CO)₆(Bu^tCP)].

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Synthesis of the first example of a metal complex containing a co-ordinated µ3-(η2-⊥) phospha-alkyne ligand. Addition of an Fe2(CO)6unit to the η2-phospha-alkyne complex [Pt(dppe)(ButCP)]: crystal and molecular structure of [Fe2Pt(dppe)(CO)6(ButCP)](dppe = Ph2PCH2CH2PPh2)