Phosphine complexes of main group elements: crystal structure of {Li[C(PMe2)3]-(tetrahydrofuran)}2
- 1 January 1984
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 569-570
- https://doi.org/10.1039/c39840000569
Abstract
The X-ray structure determination of the title compound, obtained by recrystallisation of LiC(PMe2)3 from pentane–tetrahydrofuran (thf) as colourless crystals, reveals it to be dimeric with two nearly planar (Me2P)3C-moieties linked by (thf)Li fragments via chelating and additional π-type interactions.Keywords
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