Tritertiary arsine complexes of tervalent rhodium and iridium

Abstract
A series of non-electrolyte complexes of the type [M(TTAS)X3](TTAS = bis-(o-dimethylarsinophenyl)-methylarsine, M = Rh, X = Cl, Br, I, or NO3; M = Ir, X = Cl) have been prepared and characterised. Some exist in both fac- and mer-isomeric forms. One of the isomers of [Rh(TTAS)2](CIO4)3 has been characterised.

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