Biphasic Synthesis of Hydrogen Peroxide from Carbon Monoxide, Water, and Oxygen Catalyzed by Palladium Complexes with Bidentate Nitrogen Ligands
- 1 March 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (5) , 706-708
- https://doi.org/10.1002/(sici)1521-3773(19990301)38:5<706::aid-anie706>3.0.co;2-g
Abstract
Effective and stable Pd catalysts for the biphasic synthesis of hydrogen peroxide from carbon monoxide, oxygen, and water [Eq. (a)] can be obtained by the right choice of bidentate nitrogen ligand. The best turnover numbers (578) for this reaction have been achieved with palladium complexes with 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligands.This publication has 0 references indexed in Scilit: