Electron impact studies. XL. Negative-ion mass spectra of organosulphur compounds : Thioglycollic acids and arylsulphinylamines
- 1 January 1969
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 22 (1) , 153-159
- https://doi.org/10.1071/ch9690153
Abstract
The negative-ion mass spectra of thioglycollic esters and S- alkylthioglycollic acids exhibit ions produced by simple cleavage and/or cleavage with hydrogen rearrangement. Similar spectra of arylsulphinylamines show pronounced molecular ions together with simple cleavage fragments. No skeletal-rearrangement fragments are present in the negative-ion spectra, in marked contrast with those observed in the corresponding positive-ion spectra.Keywords
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