Magnetic Coupling Relationships for Bis(metallocene)-benzene Complexes
- 1 November 1989
- journal article
- research article
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics
- Vol. 176 (1) , 527-534
- https://doi.org/10.1080/00268948908037510
Abstract
The synthesis and physical properties of meta- and para-bis(metallocene) benzene complexes with M = Fe, Co, Ni are reported. The electrochemical properties suggest greater electronic interaction between metal centers in the para-M complexes. In addition, the magnetic properties suggest different degrees of spin exchange for the meta and para complexes, with the latter exhibiting more pronounced antiferromagnetic coupling. These molecular complexes are considered prototypes for extended metallocene polymers.Keywords
This publication has 10 references indexed in Scilit:
- Synthesis of bis(3,4-dimethylcyclopentadienyl)acetylene and bridged metallocenes (.eta.5-C5Me5)M[(.eta.5-C5H2Me2)C.tplbond.C(.eta.5-C5H2Me2)]M(.eta.5-C5Me5) (M = Fe, Ni) derived therefromOrganometallics, 1988
- Syntheses of p-phenylene- and p-biphenylylene-bridged methylated binuclear ferrocenesOrganometallics, 1988
- Ferromagnetic molecular charge-transfer complexesChemical Reviews, 1988
- A generalized MO (GMO) approach to unstable molecules with quasi-degenerate electronic states:
- High-spin polycarbenes as models for organic ferromagnetsPublished by Walter de Gruyter GmbH ,1986
- Pentamethylcyclopentadienyl acetylacetonate complexes of iron(II), cobalt(II), and nickel(II). Convenient synthetic entries to mono-.eta.5-C5Me5 derivativesOrganometallics, 1985
- Synthesis, crystal structure and molecular conformations, and magnetic properties of a copper-vanadyl (CuII-VOII) heterobinuclear complex: interaction between orthogonal magnetic orbitalsJournal of the American Chemical Society, 1982
- Intervalence transfer in ligand-bridged, trimeric complexes of rutheniumInorganic Chemistry, 1976
- Ligand-bridged ruthenium complexesJournal of the American Chemical Society, 1972
- Possible ?ferromagnetic states? of some hypothetical hydrocarbonsTheoretical Chemistry Accounts, 1968