Room-temperature polymerisation of ethylene on a TiO2(anatase) surface; infrared spectroscopic evidence for an alkylidene–Ti4+polymer end-group and for a ‘hydrogen-bonding’ type of interaction of CH bonds of the polymer chain with the oxide surface
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1258-1259
- https://doi.org/10.1039/c39830001258
Abstract
An infrared spectroscopic study of the spontaneous polymerization of ethylene on a sulphate-containing TiO2(anatase) sample shows evidence for an alkylidene surface end-group of the polymer and for substantial perturbation of CH2 groups of the polymer chain by interaction with the oxide surface.Keywords
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