A new synthetic method to Mn carboxylate clusters: reductive fragmentation of [Mn12O12(O2CR)16(H2O)4] to [Mn8O2(O2CR)14(RCO2H)4] (R = CH2But)
- 27 September 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 21,p. 2502-2503
- https://doi.org/10.1039/b206751j
Abstract
The reaction of [Mn12O12(O2CCH2But)16(H2O)4] (1) with a reducing agent followed by recrystallization from CH2Cl2/MeNO2 affords the novel octanuclear complex [Mn8O2(O2CCH2But)14(ButCH2CO2H)4] (2).Keywords
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