Anomalous Elasticity of Polymer Cholesterics

Abstract
We show that polymer cholesterics have much longer pitches than comparable short molecule cholesterics, due to their anomalous elasticity. The pitch P of a chiral mixture with concentration c near the racemic (nonchiral) concentration c* diverges similar to |cc*|ν, with ν=1.43±0.04 (for short molecule cholesterics, ν=1). The short molecule law is recovered for polymers of finite molecular length once the pitch is longer than a length that diverges similar to γ with γ=0.67±0.01. Our predictions could be tested by measurements of the pitch in DNA.

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