Anomalous Elasticity of Polymer Cholesterics
- 17 April 1995
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 74 (16) , 3181-3184
- https://doi.org/10.1103/physrevlett.74.3181
Abstract
We show that polymer cholesterics have much longer pitches than comparable short molecule cholesterics, due to their anomalous elasticity. The pitch of a chiral mixture with concentration near the racemic (nonchiral) concentration diverges similar to , with (for short molecule cholesterics, ). The short molecule law is recovered for polymers of finite molecular length once the pitch is longer than a length that diverges similar to with . Our predictions could be tested by measurements of the pitch in DNA.
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