Cationic allyldinitrosyl complexes of iron
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 2,p. 459-461
- https://doi.org/10.1039/dt9860000459
Abstract
The nitrosonium salt [NO][PF6] reacts with [Fe(CO)L(NO)(η3-allyl)][L = P(OPh)3, P(OMe)3, or PPh3; allyl = C3H5, C3H4Me–1, or C3H4Me–2] to give [FeL(NO)2(η3-allyl)][PF6]. Spin saturation transfer 1H n.m.r. spectroscopy shows that the fluxionality of the products involves slow allyl rotation at room temperature.Keywords
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