The circular dichroism and the chirality of the unsymmetric-cis- and the trans-(+) D -bis(diethylenetriamine)cobalt(III) ion
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 15,p. 893-894
- https://doi.org/10.1039/c29700000893
Abstract
The circular dichroism of the systems u-cis-(+)D-[Co(dien)2]3+ and trans-(+)D-[Co(dien)2]3+ indicates the stereochemical configuration of the former, and indicates in the latter a new type of chirality which has hitherto not been realized, but which will be present in metal–polyamine complexes.Keywords
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