Highly selective generation of urethanes from amines, carbon dioxide and alkyl chlorides
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 699-700
- https://doi.org/10.1039/c39940000699
Abstract
Generation of carbamate anions from either a primary or secondary amine, carbon dioxide and a stoichiometric amount of a pentaalkylguanidine followed by the addition of alkyl chlorides gives high yields of urethanes.Keywords
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