Hydromagnesiation of 3-trimethylsilylprop-2-yn-1-ol. A simple route to (E)-3-trimethylsilylalk-2-en-1-ols

1 January 1982

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 19,p. 1126-1127
https://doi.org/10.1039/c39820001126

Abstract

Hydromagnesiation of 3-trimethyksilylprop-2-yn-1-ol affords the alkenylmagnesium halide (3) exclusively, which is valuable as a precursor of various (E)-3-trimethysilylalk-2-en-1-ols.

Keywords

TRIMETHYLSILYLPROP
TRIMETHYSILYLALK
HALIDE
TRIMETHYKSILYLPROP
TRIMETHYLSILYLALK
ALKENYLMAGNESIUM
HYDROMAGNESIATION

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