Oxygen-holes creating different electronic phases in Fe4+-oxides: successful growth of single crystalline films of SrFeO3 and related perovskites at low oxygen pressure

Abstract
We have succeeded for the first time in preparing single crystalline films of SrFeO3, CaFeO3, and Sr2FeCoO6, perovskites containing Fe4+, at low oxygen pressure of only 1 kPa, and the dominance of oxygen hole character in transport phenomena was indicated by the positive Hall coefficient of metallic SrFeO3.

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