Gibt es eine radikalische Zwischenstufe bei der Mangan(salen)‐katalysierten Epoxidierung von Alkenen?
- 18 August 1997
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 109 (16) , 1802-1803
- https://doi.org/10.1002/ange.19971091615
Abstract
No abstract availableKeywords
This publication has 25 references indexed in Scilit:
- X‐Ray Structural Studies of Highly Enantioselective Mn(salen) Epoxidation CatalystsChemistry – A European Journal, 1996
- Selective Catalytic Oxidation of Substrates That Bind to Metalloporphyrin Enzyme Mimics Carrying Two or Four Cyclodextrin Groups and Related MetallosalensJournal of the American Chemical Society, 1996
- Direct Measurements of Unimolecular Radical Kinetics Employing Ultrafast Radical Rearrangements as ReportersJournal of the American Chemical Society, 1996
- On the Chirality Transfer in the Epoxidation of Alkenes Catalyzed by Mn(salen) ComplexesJournal of the American Chemical Society, 1995
- A reassessment of the isoinversion principleJournal of the Chemical Society, Chemical Communications, 1995
- Nonstereospecific Mechanisms in Asymmetric Addition to Alkenes Result in Enantiodifferentiation after the First Irreversible StepJournal of the American Chemical Society, 1994
- Mechanistic study of a synthetically useful monooxygenase model using the hypersensitive probe trans-2-phenyl-1-vinylcyclopropaneThe Journal of Organic Chemistry, 1991
- Alkene epoxidations catalyzed by iron(III), manganese(III), and chromium(III) porphyrins. Effects of metal and porphyrin substituents on selectivity and regiochemistry of epoxidationJournal of the American Chemical Society, 1989
- Intermediates in the epoxidation of alkenes by cytochrome P-450 models. 5. Epoxidation of alkenes catalyzed by a sterically hindered (meso-tetrakis(2,6-dibromophenyl)porphinato)iron(III) chlorideJournal of the American Chemical Society, 1989
- Olefin epoxidation by manganese (IV) porphyrins: evidence for two reaction pathwaysJournal of the American Chemical Society, 1987