Structure of Isobutylene

Abstract
The microwave spectrum of (CH3)2C=C13H2, CH3C13H3C=CH2, and (CH3)2C=CHD has been studied in the region 8–40 kMc/sec. The effective rotational constants of these species combined with previous microwave data give the structural parameters: rCC(single)=1.507 Å, rCC(double)=1.330 Å, average rCH(methyl)=1.08 Å, rCH(ethylenic)=1.088 Å, average <HCH (methyl)=107°, <HCH (ethylenic)=118.5°, <CCC=115.3°.
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