The three-membered metallacyclic structure of (η5-C5H5)2ZrCl-substituted dimethyl ether

Abstract
The title compound cp2Z[graphic omitted]Me (3)(cp =η5-C5H5) was prepared by treating cp2ZrCl2 with MeOCH2MgCl in CH2(OMe)2; a three-membered metallacyclic onium-type structure was observed by X-ray diffraction.

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